Experimental investigations on partition coefficients of first-transition row elements between olivine and silicate melt

New partitioning coefficients of first-transition row elements, Ga and Ge between olivine and silicate melt have been reported. Our new high-temperature experiments have investigated the effects of oxygen fugacity and iron content on these partition coefficients. This newly compiled dataset offers insights into interpreting trace elements found in olivine phenocrysts within lunar basalts, shedding light on the deep interior composition of the Moon.

Olivine is the earliest mineral to crystallize from basaltic magma, and accurate knowledge of olivine/melt partition coefficients (D^Ol-melt) for first-transition row elements (FTREs) Ga and Ge, is required in quantitative modeling of petrogenetic processes in planetary basalts. Numerous experimental studies have focused on this topic, but most investigations concentrated on minor elements found in olivine, and the oxygen fugacities (fO₂) in many of these experiments were commonly designed to be similar to those found in Earth’s mantle. However, for applications involving the formation of basalt on other rocky planetary bodies including the Moon, Mars, and asteroids, oxygen fugacities during basalt formation can range widely from 2 log units below the iron-wüstite buffer (herein referred to as IW-2) to IW+6. In addition, lunar basalts are generally iron-rich compared to terrestrial basalts.
To assess the effects of oxygen fugacity and iron content on partition coefficients of FTREs, Ga and Ge, Dr. Jiejun Jing (a JSPS postdoctoral fellow in Ehime University) conducted a series of high-temperature experiments (around IW-2 to IW+5.5) at 1 atm using a gas-mixing furnace with the cooperation of colleagues in Ehime University, and in other universities in the Netherlands, China and Germany. The results show that most D^Ol-melt show no sensitivity to bulk system iron contents, but D^Ol-melt_Cr is significantly higher in our experiments compared to D^Ol-melt_Cr derived from olivine-melt inclusion pairs in lunar samples with much higher FeO content. D^Ol-melt_Ni values are nearly constant at a range of oxygen fugacities above the IW buffer, but abruptly decrease when the system is iron metal saturated (below the IW buffer). Using the newly derived partition coefficients, the authors re-assessed two aspects of lunar basalt generation. First, they conclude that the Cr-rich nature of the olivines in lunar basalts compared to terrestrial basalts must be attributed to the Cr-nature of the cumulate mantle source of lunar basalts, which is linked to the early crystallization of Cr-poor minerals olivine and orthopyroxene in the lunar magma ocean resulting in shallow Cr-rich cumulates. Second, the higher Co/Ni ratios in olivine in high-titanium lunar basalts compared to olivine in low-titanium lunar basalts suggest the former were formed at a more reduced condition in the lunar mantle (below the IW buffer, saturated with metal).

Reference URL: https://www.sciencedirect.com/science/article/pii/S0016703724001510

Bibliographic Information

Experimental investigation of first-row transition elements partitioning between olivine and silicate melt: Implications for lunar basalt formation.
Jing, J. J., Su, B. X., Berndt, J., Kuwahara, H., & van Westrenen, W.
Geochimica et Cosmochimica Acta, 373, 211-231,
https://doi.org/10.1016/j.gca.2024.03.028.

Fundings

• Vici grant (865.13.006) from the Dutch Research Council
• China Scholarship Council fellowship (201904910721)
• Ministry of Science and Technology National Key R&D Program of China (No. 2022YFC2903501)
• National Natural Science Foundation of China (42350001)

Media

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  Back-scattered images of recovered samples

  Olivine (Ol) and silicate melt (quenched as glass) were recovered from a gas-mixing furnace at 1 atm and 1400 °C. The starting material powders were loaded in a noble capsule and heated in the furnace for 72 hours at different oxygen fugacities. Laser-ICP-MS was used to measure the trace elements in olivine and glass.

  credit : Jiejun Jing
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